IUPAC Nomenclature

#Chemistry
IUPAC Abbreviation

Naming Noncyclic Molecules

$$
\begin{align}
\text{Let } C & = \text{alkyl prefix} \\N & = \text{number of minor substituents}\\M & = \text{number of major substituent} \\m & = \text{prefix of major substituent} \\n_{i} & = \text{number of }i\text{th substituents} \\p_{i} & = \text{numeric prefix for }i\text{th substituent}\\s_{i} & = \text{prefix for }i\text{th substituent} \\c_{i} & = \text{carbon number for }i\text{th substituent} \\S_{i} & = \text{stereochemistry for }i\text{th substituent if present} \\\end{align}
$$
$$
\text{Name} = (c_{1}S_{1},\ldots c_{N}S_{N})-c_{1},\ldots c_{n_{1}}-p_{1}s_{1}-\ldots -c_{N},\ldots c_{n_{N}}-p_{N}s_{N}C-c_{m_{1}},\ldots c_{m_{M}}-p_{m}m
$$

Example

The below molecule is named 3-ethylheptanol

CCCC(CC)CCCO

Steps

  1. Name the longest carbon chain
  2. . Number the chain
  3. Name substituents
  4. Assign a number to each substituent
  5. Complete the name
ClassPrefix NameSuffix Name
Carboxylic Acidcarboxy-oic acid
Esteralkoxycarbonyl-oate
Amideamido-amide
Nitrilecyano-nitrile
Aldehydeformyl (--CH=O)-al
Ketoneoxo (=O)-one
Alcoholhydroxy-ol
Thiolmercapto--thiol
Amineamino-amine
Alkenealkenyl-ene
Alkynealkynyl-yne
Alkanealkyl-ane
EtheralkoxyN/A
Alkyl HalidehaloN/A