IUPAC Nomenclature
#Chemistry
IUPAC Abbreviation
Naming Noncyclic Molecules
$$
\begin{align}
\text{Let } C & = \text{alkyl prefix} \\N & = \text{number of minor substituents}\\M & = \text{number of major substituent} \\m & = \text{prefix of major substituent} \\n_{i} & = \text{number of }i\text{th substituents} \\p_{i} & = \text{numeric prefix for }i\text{th substituent}\\s_{i} & = \text{prefix for }i\text{th substituent} \\c_{i} & = \text{carbon number for }i\text{th substituent} \\S_{i} & = \text{stereochemistry for }i\text{th substituent if present} \\\end{align}
$$
$$
\text{Name} = (c_{1}S_{1},\ldots c_{N}S_{N})-c_{1},\ldots c_{n_{1}}-p_{1}s_{1}-\ldots -c_{N},\ldots c_{n_{N}}-p_{N}s_{N}C-c_{m_{1}},\ldots c_{m_{M}}-p_{m}m
$$
- $\displaystyle C$: Alkyl Prefixes
Example
The below molecule is named 3-ethylheptanol
CCCC(CC)CCCO
Steps
- Name the longest carbon chain
- . Number the chain
- Name substituents
- Assign a number to each substituent
- Complete the name
| Class | Prefix Name | Suffix Name |
|---|---|---|
| Carboxylic Acid | carboxy | -oic acid |
| Ester | alkoxycarbonyl | -oate |
| Amide | amido | -amide |
| Nitrile | cyano | -nitrile |
| Aldehyde | formyl (--CH=O) | -al |
| Ketone | oxo (=O) | -one |
| Alcohol | hydroxy | -ol |
| Thiol | mercapto- | -thiol |
| Amine | amino | -amine |
| Alkene | alkenyl | -ene |
| Alkyne | alkynyl | -yne |
| Alkane | alkyl | -ane |
| Ether | alkoxy | N/A |
| Alkyl Halide | halo | N/A |