Perturbation Theory

#Physics

Quantum Physics

Topics

$\displaystyle E_{n}^{1}=\braket{ \psi_{n}^{0} | H'| \psi_{n}^{0} }$

  • First order correction to energy
  • $\displaystyle H'$ is the perturbation
  • $\displaystyle \psi_{n}^{0}$ is the unperturbed state

$\displaystyle \psi_{n}^{1}=\sum_{m \neq n}^{} \frac{\braket{ \psi_{m}^{0}|H' | \psi_{n}^{0} }}{(E_{n}^{0}-E_{m}^{0})}\psi_{m}^{0}$

  • First-order correction to wave function of perturbation

$\displaystyle E^{2}{n}=\sum{m \neq n}^{} \frac{\lvert \braket{ \psi_{m}^{0}|H' | \psi_{n}^{0} }\rvert^{2}}{E_{n}^{0}-E^{0}_{m}}$

  • Second order correction to energy